东部草原露天矿黏土对磷的养分动力学特性研究

Phosphorus dynamics of clay in Eastern grassland open pit mining area

  • 摘要: 东部草原露天矿区土地瘠薄、草场退化严重,生态修复成为必然。矿区草原表土缺乏,露天矿开采产生的生黏土资源化利用成为矿区生态修复的一种可行方法。磷是植物必需营养元素且在土壤中难移动,磷在不同黏土组成中的养分动力学特性对于合理利用黏土具有重要的现实意义。对黏土、表土、沙土、黏土沙土1∶1混合(NS1∶1)、黏土沙土1∶2混合(NS1∶2)、黏土沙土1∶3(NS1∶3)混合等6种土壤基质对磷的吸附解吸进行对比分析,发现均符合Langmuir和Freundlich等温吸附模型,黏土中磷元素的最大吸附量(Γmax)、最大缓冲量(MBC)、磷零点吸附平衡液浓度(EPC0)、磷吸持指数(PSI)、磷元素饱和度(DPS)等,均表现出黏土和黏土∶沙土1∶1混合固定磷元素能力强于表土,其中黏土的Γmax是表土的2.61倍,黏土∶沙土1∶1是表土的2.21倍。在解吸的过程中,沙土的解吸率高达91%,而解吸量只有91.3 mg/kg;而黏土∶沙土1∶1混合的解吸率是40.4%,解吸量为395.92 mg/kg,是表土和黏土解吸的1.51倍和1.29倍。黏土和沙土1∶1混合在吸附磷和解吸磷两方面都表现出了最优效果。

     

    Abstract: The surface soil in eastern prairie open-pit mining area is poor and the grassland degradation is serious. Eco- logical restoration is inevitable. The surface soil of grassland mining area is insufficient,and the utilization of raw clay produced by open pit mining has become a feasible method for ecological restoration of mining area. Phosphorus is an essential nutrient element for plants and it is difficult to move in soil. The nutrient dynamics of phosphorus in different clay compositions has practical significance for rational utilization of clay. The adsorption and desorption of phosphorus on clay,surface soil,sandy soil,the mixture of clay and sandy soil in 1 ∶ 1 ratio ( NS1 ∶ 1),the mixture of clay and sandy soil in 1 ∶ 2 ratio (NS1 ∶ 2),and the mixture of clay and sandy soil in 1 ∶ 3 ratio ( NS1 ∶ 3) were compared and analyzed. It was found that the adsorption and desorption isotherms of phosphorus in clay were in accordance with Langmuir and Freundlich adsorption and desorption isotherms,and the maximum adsorption capacity (Γmax ) and maxmum buffer of phosphorus in clay were in accordance with Langmuir and Freundlich adsorption and desorption A- mount (MBC),equilibrium solution concentration (EPC0 ),phosphorus adsorption index (PSI),phosphorus saturation (DPS) and so on,all showed that the ability of fixing phosphorus element with clay and the mixture of clay and sand in 1 ∶ 1 ratio is stronger than surface soil,of which clay Γmax is 2. 61 times of surface soil,clay Γmax is 2. 21 times of surface soil. In the desorption process,the desorption rate of sandy soil is as high as 91% ,and the desorption amount is only 91. 3 mg / kg,the desorption rate of 1 ∶ 1 mixture of clay and sandy soil is 40. 4% and the desorption capacity is 395. 92 mg / kg,which is 1. 51 and 1. 29 times of that with surface soil and clay. The 1 ∶ 1 mixture of clay and sand showed the best effect in two aspects:phosphorus adsorption and phosphorus desorption.

     

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