废润滑油对城市污泥水煤浆成浆性能的影响机制

Influence mechanism of waste lubricating oil on slurry characteristics of municipal sludge coal water slurry

  • 摘要: 城市污泥焚烧不仅能有效控制污泥处理过程中的二次污染,还能充分利用污泥的热值。 但 直接将城市污泥添加至水煤浆,会降低其流动性和发热量,不利于水煤浆的气化或燃烧。 由于废润 滑油具有较高的发热量和较好的流动性,利用废润滑油与污泥水煤浆进行掺混,提高污泥水煤浆的 发热量并改善其流动性。 实验结果表明:泥油比(质量比)为 1.0 时,随着干基污泥质量分数从 0 增 到 12%时,水煤浆表观黏度逐渐减小;泥油比为 1.1 时,水煤浆表观黏度呈先增加后减小的变化规 律,干基污泥质量分数为 3%时,水煤浆表观黏度最大。 污泥水煤浆表观黏度随泥油比的增加而增 加。 水煤浆发热量为 17.42 MJ / kg、泥油比为 1.0 时,干基污泥质量分数从 0 增到 6%,水煤浆的表 观黏度从 714 mPa·s 降低到 340 mPa·s,降幅约为 52.3%。 红外光谱分析显示,污泥和煤粉被废 润滑油浸泡后,非极性官能团峰明显增强,而极性官能团峰明显减弱。 X 射线能谱分析显示,经废 润滑油浸泡后,污泥和煤粉的 O/ C 原子比分别从 0.88 和 0.23 急剧降至 0.04 和 0.08,其 C—H/ C—C含量分别从 53.98%和 70.44%增到 93.24%和 86.83%。 润湿性分析显示,经废润滑油浸泡后, 污泥和煤粉的接触角分别从 69.5°和 63.4°增加到 101.3°和 94.2°,且接触角基本不随接触时间的增 加发生变化。 废润滑油的长链烷烃和苯环可吸附在煤粉与污泥表面,减少煤粉与污泥表面的亲水 位点,从而促进污泥和煤粉在分散剂的作用下形成较完整的水化膜,这是废润滑油改善污泥水煤浆 成浆性能的主要原因。

     

    Abstract: Municipal sludge incineration can not only effectively solve some secondary pollution problems occurred in the process of sludge treatment,but also maximize the utilization of the calorific value of municipal sludge. The addition of municipal sludge would deteriorate the fluidity and calorific value of sludge coal water slurry (SCWS),which is not conducive to the gasification or combustion of the SCWS. Due to the high calorific value and good fluidity of waste lubricating oil,the slurry ability of the SCWS could be improved by adding waste lubricating oil into the SCWS. The experimental results show that the apparent viscosity of the SCWS decreases gradually with the increase of municipal sludge content from zero to 12% under the sludge oil ratio of 1.0. However,under the sludge oil ratio of 1.1,the apparent viscosity of the SCWS increases first and then decreases gradually with the increase of municipal sludge content. The apparent viscosity of the SCWS reaches the maximum with the dry basis sludge content of 3%. Basically,the apparent viscosity of the SCWS increases with the increase of sludge oil ratio. The apparent viscosity of the SCWS decreases about 52.3% from 714 mPa·s to 340 mPa·s with the increase of municipal sludge content from zero to 6% under the sludge oil ratio of 1.0 and the SCWS calorific value of 17.42 MJ/kg. According to the infrared spectrum analysis results,when the municipal sludge and coal powder are soaked in waste lubricating oil,the peaks of non polar functional groups are obviously enhanced,while the peaks of polar functional groups are obviously weakened. Based on the results of X ray energy spectrum analysis,the O/C ratio of municipal sludge and coal powder decreases sharply from 0.88 and 0.23 to 0.04 and 0.08,respectively,and the C—H/C—C content increases from 53.98% and 70.44% to 93.24% and 86.83%,respectively. On the basis of wettability results,the contact angles of municipal sludge and coal powder increases from 69.5° and 63.4° to 101.3° and 94.2°,respectively,and the contact angle exhibits little change with the increase of contact time. The above analysis results show that the long chain alkane and benzene ring of waste lubricating oil can be adsorbed on the surface of municipal sludge and coal powder and result in the decrease of the hydrophilic site on the solid surface,which is beneficial for the formation of a relatively complete hydration film around the municipal sludge and coal powder. This is the main reason behind for the enhanced slurry performance of the SCWS in the presence of waste lubricating oil.

     

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